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排序方式: 共有8391条查询结果,搜索用时 15 毫秒
991.
Purushottam B. Tiwari Prem P. Chapagain Ahmed Seddek Thirunavukkarasu Annamalai Aykut Üren Yuk-Ching Tse-Dinh 《ChemMedChem》2020,15(7):623-631
A topoisomerase-DNA transient covalent complex can be a druggable target for novel topoisomerase poison inhibitors that represent a new class of antibacterial or anticancer drugs. Herein, we have investigated molecular features of the functionally important Escherichia coli topoisomerase I (EctopoI)-DNA covalent complex (EctopoIcc) for molecular simulations, which is very useful in the development of new antibacterial drugs. To demonstrate the usefulness of our approach, we used a model small molecule (SM), NSC76027, obtained from virtual screening. We examined the direct binding of NSC76027 to EctopoI as well as inhibition of EctopoI relaxation activity of this SM via experimental techniques. We then performed molecular dynamics (MD) simulations to investigate the dynamics and stability of EctopoIcc and EctopoI-NSC76027-DNA ternary complex. Our simulation results show that NSC76027 forms a stable ternary complex with EctopoIcc. EctopoI investigated here also serves as a model system for investigating a complex of topoisomerase and DNA in which DNA is covalently attached to the protein. 相似文献
992.
Production of Synthesis Gas via Dry Reforming of Methane over Co‐Based Catalysts: Effect on H2/CO Ratio and Carbon Deposition 下载免费PDF全文
Ahmed A. Ibrahim Muhammad Awais Naeem Anis H. Fakeeha Wasim Ullah Khan Ahmed S. Al‐Fatesh Ahmed E. Abasaeed 《化学工程与技术》2015,38(8):1397-1405
The effect of support type on synthesis gas production using Co‐based catalysts supported over TiO2‐P25, Al2O3, SiO2, and CeO2 was investigated. The catalysts were prepared by the incipient wet impregnation method and characterized by various techniques for comparison. Experiments were performed in a micro tubular reactor. The results revealed that all Co‐supported catalysts produced synthesis gas ratios of 1 and below and, thus, proved to be well‐suited for methanol and Fischer‐Tropsch syntheses. Co catalysts supported over TiO2‐P25 and Al2O3 provided better synthesis gas ratios and stability performances. The promotion of a Co/TiO2‐P25 catalyst with Ce had a substantial influence on its catalytic activity and the amount of carbon deposit. A Ce‐promoted catalyst diminished markedly the extent of carbon deposition and thus boosted the performance towards better activity and stability. 相似文献
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Ahmed El Kholy Khairy Fakhry Osayed Abu-Elyazeed 《Journal of Nuclear Science and Technology》2019,56(3):291-299
Heat transfer study of nanofluids as coolant in SCWRs core has been performed at Helwan University. A thermal hydraulic code has been produced to study the effect of TiO2 nanofluid water based as a coolant with comparison with pure water as a coolant. Various volume fractions of nanoparticles TiO2 (2, 6 and 10%) were used in order to investigate its effects on reactor thermalhydraulic characteristics. Based on Parameters of a SCW Canadian Deuterium Uranium nuclear reactor (CANDU), the fuel assembly was modeled to study the effect of nanoparticles volume fraction on thermos-physical properties of basic fluid and the temperature distribution of fuel, cladding surface and coolant in axial direction. The theoretical results showed that the density, viscosity and thermal conductivity of the coolant increases with the increase of nanoparticles volume fraction, contrasting to specific heat, which decreases with the increase in nanoparticles volume fraction. 相似文献
996.
Bakhtiar Ul Haq S. AlFaify Thamraa Alshahrani R. Ahmed Q. Mahmood S.A. Tahir Hala H. Alhashim A. Laref 《Ceramics International》2021,47(3):3380-3388
The development of materials in two-dimensions has been established as an effective approach to improve their thermoelectric performance for renewable energy production. In this article, we generated monolayers of the orthorhombic structured lead-chalcogenides PbX (X = S, Se, and Te) for room-temperature thermoelectric applications. The Density functional theory and semiclassical Boltzmann transport theory-based computational approaches have been adopted to carry out this study. The band structures of PbX monolayers exhibited narrow indirect bandgaps with a large density of states corresponding to their bandgap edges. Accordingly, substantial electrical conductivities and Seebeck coefficients have been obtained at moderate level doping that has caused significant thermoelectric power factors (PFs) and figures-of-merit (zT) ~1. The single-layered PbX showed anisotropic dispersion of electronic states in the band structure. A relatively lighter effective mass of charge carriers has been extrapolated from the bands oriented in the y-direction than that of the x-direction. As a result, the electrical conductivities and PFs have been observed larger in the y-direction. The optimum PFs recorded for single-layered PbS, PbSe, and PbTe in y-direction amounts to 9.90 × 1010 W/mK2s at 1.0 eV, 10.40 × 1010 W/mK2s at 0.82 eV, and 10.80 × 1010 W/mK2s 0.66 eV respectively. Moreover, a slight increase in p-type doping is found to improve the x-component of the PF, whereas n-type doping has led to improvement in the y-component of PF. Our results show an improved thermoelectric response of PbX monolayer (PbTe in particular) than their bulk counterparts reported in the literature, which indicates the promise of PbX monolayers for nanoscale thermoelectric applications at room temperature. 相似文献
997.
Krystal Archer Zuzana Broskova Ahmed S. Bayoumi Jian-peng Teoh Alec Davila Yaoliang Tang Huabo Su Il-man Kim 《International journal of molecular sciences》2015,16(10):23651-23667
Cardiovascular disease is the leading cause of death in the United States, accounting for nearly one in every seven deaths. Over the last decade, various targeted therapeutics have been introduced, but there has been no corresponding improvement in patient survival. Since the mortality rate of cardiovascular disease has not been significantly decreased, efforts have been made to understand the link between heart disease and novel therapeutic targets such as non-coding RNAs. Among multiple non-coding RNAs, long non-coding RNA (lncRNA) has emerged as a novel therapeutic in cardiovascular medicine. LncRNAs are endogenous RNAs that contain over 200 nucleotides and regulate gene expression. Recent studies suggest critical roles of lncRNAs in modulating the initiation and progression of cardiovascular diseases. For example, aberrant lncRNA expression has been associated with the pathogenesis of ischemic heart failure. In this article, we present a synopsis of recent discoveries that link the roles and molecular interactions of lncRNAs to cardiovascular diseases. Moreover, we describe the prevalence of circulating lncRNAs and assess their potential utilities as biomarkers for diagnosis and prognosis of heart disease. 相似文献
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Lili Cai Xiao-Yu Wu Xuefeng Zhu Ahmed F. Ghoniem Weishen Yang 《American Institute of Chemical Engineers》2020,66(7):e16427
Precombustion carbon capture is an effective strategy to reduce large-scale CO2 emissions, which is mainly used in the area of integrated gasification combined cycle (IGCC) power plants. Oxygen transport membranes (OTMs) were suggested as the air separation unit to produce high purity oxygen for the gasifier. However, the improvement in efficiency was limited. Here, a new IGCC process is reported based on a robust OTM reactor, where the OTM reactor is used behind the coal gasifier. This IGCC-OTM process fulfills syngas oxidation, H2 production, and carbon capture in one unit, thus a significant decrease of the energy penalty is expectable. The membrane reactor does not use noble metal components, and exhibits high hydrogen production rates, high hydrogen separation factor (103–104), and stable performance in a gas mixture mimicking real syngas compositions from a coal gasifier with H2S concentrations up to 1,000 ppm. 相似文献